Well, to add further to my confusion... I was at the boat today and was happy to notice the lack of boat funk when I opened her up. (I replaced all sanitation hose a couple of weeks ago, so I was happy to see the improvement.)
While I was working on my electrical panel over the chart table, I kept getting a whiff of "head smell". Knowing I was near the vent, I sniffed around but found nothing so I went to check the head itself. I found a solo cup or two's worth of dirty water in the head. I flushed, filled the head with fresh water from the sink, and pumped it into the tank and, when I was done, it gurgled at me. Repeatedly.
I assumed the holding tank must be pressurized again, so I uncovered it, moved the cushions, and found the top to be bowed up enough to have raised the wooden cover. I covered the vent with a towel, and undid the vent hose clamp. I worked the hose off and relieved the pressure but got no liquid out, only foul air. I used my foot to mash/pump the top of the tank and the vent elbow breathed fine... again all air, no liquid came out. I used a piece of clean hose and a double barb to attach to the vent hose so I could blow on it and judge the extent of the blockage. There was a bit of water in the line at a low point and I had to blow that out, but no blockage.
Now fella's I'm an engineer and while I might have forgotten a lot, I'm certain that if that vent wasn't blocked, the pressure couldn't build, or at least could only build to the pressure needed to blow that water out of the vent (a problem for another day). I'm equally certain that the pressure it took to blow that water out was nothing compared to the pressure required to expand the tank and force funky air past my joker valve and into the bowl.
Thoughts, ideas, crazy theories... all welcome at this point.
As an aside, while the vent hose was disconnected we had quite a rainstorm and the rainwater started coming down the hose. I don't know if the vent is so low to the deck that it backfills when a puddle forms by the scuppers or not, but there's another reason for me to replace that vent line with one that comes out through the hull. No need to fill that tank with rainwater!